Methylene Blue Adsorption Kinetics Investigation by Coconut Shell Activated Carbon Adsorbent Using Fractional Power, Avrami and Bangham Models

Abstract

Methylene blue is not easily biodegradable, and its persistence in water can contribute to long-term contamination if not properly treated. Numerous adsorption kinetic study successes were achieved utilizing activated carbons of coconut shell, especially the Pseudo-First and Pseudo-Second order models with little/no regards to the unique behavior described by the Avrami, Bangham and the Fractional Power kinetic models. The parameters in those models are determined to describe the sorption mechanism. Avrami model fitting results suggests a complex adsorption process, which does not follow the first-order kinetic. Obtained results show that the Fractional Power model best described the Coconut Shell-Activated Carbon Methylene blue bio-sorption process at constant adsorption capacity of 15937.8 mg/g. Findings show that Bangham kinetic model does not fit the experimental data for Methylene blue sorption from aqueous solution. Methylene blue exposure issues like gastrointestinal discomfort, skin and eye irritation, and imbalances in the populations of various species in aquatic ecosystems due to impacts on their growth, reproduction and survival, may be solved using a very effective adsorbent, such as the Coconut Shell -Activated Carbon used here.  

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Authors

1. 1National Institute of Construction Technology and Management (NICTM) Uromi, Ugboha Road, Edo State, NIGERIA
2. 2Modibbo Adama University,Yola, Adamawa State, NIGERIA
3. 3Federal College of Horticulture Dadin Kowa, Gombe State, NIGERIA
4. 4Department of Petroleum and Gas Engineering, BUITEMS QUETTA, Balochistan, PAKISTAN
5. 5Adhiyamaan College of Agriculture and Research, Tamilnadu, INDIA